sulfuric acid immobilized on silica: a versatile and reusable heterogeneous catalyst for the synthesis of phenanthrimidazole derivatives
نویسندگان
چکیده
a new, convenient, efficient, and cost-effective one-pot synthesis of 1hphenanthro[9,10]imidazol-2-yl from phenanthraquinone and aldehydes, using sulfuric acidimmobilized on silica as catalyst is described. the present methodology offers severaladvantages such as excellent yields, simple procedure, shorter reaction times, the use ofinexpensive reagents, easy recovery and eco-friendly. in addition to these, 2-alkylphenanthrimidazole is obtained from triethyl orthoesters in good yields.
منابع مشابه
Sulfuric acid immobilized on silica: A versatile and reusable heterogeneous catalyst for the synthesis of phenanthrimidazole derivatives
A new, convenient, efficient, and cost-effective one-pot synthesis of 1Hphenanthro[9,10]imidazol-2-yl from phenanthraquinone and aldehydes, using sulfuric acidimmobilized on silica as catalyst is described. The present methodology offers severaladvantages such as excellent yields, simple procedure, shorter reaction times, the use ofinexpensive reagents, easy recovery and eco-friendly. In additi...
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silica sulfuric acid as an efficient and reusable heterogeneous catalyst has been used for the preparation of amidines 2 from formimidate 1 by reaction with aromatic amines at room temperature in good to excellent yields. imidate was prepared by treatment of equimolar quantities of triethyl orthoformate and diaminomaleonitrile in refluxing dioxane. all the compounds were characterized fully by ...
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عنوان ژورنال:
journal of the iranian chemical researchجلد ۲، شماره ۳، صفحات ۱۸۳-۱۸۷
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